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Week of September 8, 2009
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Chemistry Period 3 Archived Notes

 
September 8, 2009

 

 

Homework:


Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Safety Skit (9-11)

Significant Figures Worksheet odds (9-9)

 
Classwork:
 
Period 3:
 

Uncertainty in Measurement

 

*** When making a measurement, you must give all the certain (or exact) digits that the instrument can give + one additional “uncertain” digit that you estimate***

 

-         Measuring instruments always have some built in flaws

-         Measurement always involves some estimation

 

On an electronic balance:

-         The measurement is done for you.  The last number on the screen is the uncertain digit

o       Be sure to include the unit as well as the measurement

 

On a scale:

-         Imagine a graduated cylinder- measures volume

o       Liquids curve in the cylinder (known as the meniscus)

o       Measurements are taken from the bottom of the bend

-         The certain digits are those given on the graduated cylinder.

o       The uncertain digit is found by reading between the lines of the instrument

 

The Uncertainty of a Measurment

-         Generally, the uncertainty of a measurement reflects the value of the uncertain digit:

Suppose the measurement was: 32.7 mL

§         The seven in this measurement is uncertain.

§         Since the seven is uncertain, it could possibly as high as an 8 or as low as a 6.

§         Therefore the uncertainty is +/- .1

 

Reliability in Measurement

 

-         Precision- several measurements that are close in value

-         Accuracy- how close a measurement is to the accepted value (a standard)

 

Reliable measurements have both high precision and high accuracy.

Can you have one without the other???

 

1-6 Significant Digits

 

-         When combining numbers in calculations, the uncertainty of the measurements must be considered in the final answer- this is done by keeping tract of significant figures

 

-         Significant digits: The certain digits and the uncertain digit make up the significant digits

 

Non- Significant Zeros:

-         As a place keeper- not significant:

o       If the zero is not a known digit, or an estimated digit, the number is not significant

-         Zeros to the Right of a number without a decimal point:

1040 – 3 significant figures

1040. – 4 significant figures

104 – 3 significant figures

1000 – 1 significant figure

1000. – 4 significant figures

1000 – 2 significant figures (the line tells that that zero is the uncertain digit.

-         The Atlantic Pacific rule???

 

More Information on Zeros:

 

Zeros to the right of the decimal place before a whole number are not significant.  .001 has only one significant figure. .0000001 also only has one significant figure.

 

Zeros between two whole numbers are significant.  1.01, now has 3 significant figures.  .0101 also has 3 significant figures.

 

Numbers following a whole number:

If a decimal place is not present, the zeros to the right of the number are not significant unless marked with a bar.  So, 1000 has only one significant figure.

 

If a decimal place is present, the zeros to the right of the number are significant.  So 1000. has 4 significant figures.

 

Zeros following a whole number after a decimal are significant. So, in the number 14.000 the three zeros are significant so there are 5 significant figures.  .0002012300 has 7 significant figures.  Remember, those first three zeros are not significant, but the ones following the three are significant.

 

Significant Digits in Calculations:

 

            Rule for exact numbers

           

When an exact number appears in a calculation, it does not effect the significant digits of the calculations

           

                        **All Defined Value Unit Factors are Exact Numbers**

 

            Rule for addition and subtraction of measurements:

 

Find the measurement with the most uncertainty (fewest number of decimal places) and round the answer to that uncertainty.

 

Ex.  4.5 g + 3.221 g + 4.3232 g = ?

 

            4.5 has an uncertainty of .1

            3.221 has an uncertainty of .001

            4.3232 has an uncertainty of .0001

 

So, the number with the most uncertainty is 4.5 with an uncertainty of .1, therefore, the answer must be rounded off to that uncertainty (in this case, one decimal place)

 

The Math: 

12.0442 is the answer so far, but remember to correct for uncertainty the answer may only have one decimal place.  In this case, 0 should be the last significant figure.  Look to the right of zero, notice that it is a four.  Since it is a four, we need to round that four down.  The zero does not change, so the answer to the question would become 12.0 +/- .1 g.

 

            Rule for multiplication or division of measurements:

                       

Find the measurement with the fewest number of significant figures and round the answer to that number of significant figures.

                        Ex. 5.32 g x .01 g

                                   

5.32 has 3 significant figures and .01 has 1 significant figure, so the answer to the problem must have only one significant figure.

 

The answer is .0532.  Remember, now you need to correct for significant figures.  Since the answer can only have one significant figure, anything after the 5 must be rounded off.  Since 3 is less than five, it is rounded down, and the five does not change.  The answer to this problem then is .05 (one significant figure).

 

Scientific notation:

 

Scientific measurements usually appear in the form of scientific notation, written in the general form as:

 

t.tt x 10n  where t is any integer and n is the some whole number of times that 10 has been multiplied to reach a given answer.

 

Rule # 1

Find the first non-zero significant figure in a number and place the decimal place immediately to the right of that number.

                        Rule # 2

IF the decimal was moved to the left, then the power of 10 is a positive number

 

IF the decimal was moved to the right, then the power of 10 is a negative number

 

Remove all non-significant numbers (place holding zeros)

 

Example:

 

Write .00923 in scientific notation:

 

Ok, since the 2 zeros are place holders, they will not appear in the final answer.

 

The fist non-zero sig fig is the 9, so place the decimal after the 9

            9.23

Now, since the decimal was moved to the right 3 places, the power of ten is a – number

 

                                    9.23 x 10-3

            Write 5600 in scientific notation:

 

Ok, the first sig fig is the 5, so place the decimal immediately to the right of the 5

                                                            5.600

           

Since the two zeros are not significant, they should not appear in the final answer:

 

            5.6

 

Since the decimal was moved to the left three place, the power of 10 is a positive number:

 

5.6 x 103 (to check to see if you have done this correctly simply revert to the ordinary number)

 

Since 103 is 10 x 10 x 10, 5.6 is being multiplied by 1000.  when 5.6 is multiplied by 1000, the answer becomes 5600

 

 

Period 4:
 
no class
 
 

September 9, 2009

 

 

Homework:


Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Safety Skit (9-11)

Significant Figures Worksheet even (9-11)

 
Classwork:
 
Period 3:
 

class time to go over sig fig worksheet odds; outline 1.3; and work on safety skit

 

Period 4:
 
no class
 
 

September 10, 2009

 

 

Homework:


Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Safety Skit (9-11)

Significant Figures Worksheet even (9-11)

 
Classwork:
 
Period 3:
 

no class

 

Period 4:
 
no class
 
 

September 11, 2009

 

 

Homework:


Ion Quiz 1-18 (9-18)
Element Icosohedron (10-13)
Concept Map and OUtline 2.1, 2.2, and 2.3 (9-15)
Lab Safety Quiz (9-14)
Lab Equipment Quiz (9-17)
2 Worksheets on Elements (9-14)
Test Chapters 1/2 (9-23)

 
Classwork:
 
Period 3:
 

lab safety skits

 

introduction to concept mapping

 

Period 4:
 
lab safety video