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Week of August 31, 2009
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Chemistry Period 7 Archived Notes

 
August 31, 2009

 

Homework:

 

Text Books Covered (9-4)
Rules and Regulations Signed and Returned (9-2)
Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Text Book Scavenger Hunt (9-2)
Read Section 1.1 and 1.4 (9-2)

 
Classwork:
 
Period 7:
 
Introduction to classroom rules and regulations and web site
 
Period 8:
 
Brief explanation of ions and icosohedron assignment
 
class time to work on text book scavenger hunt
 

 

September 1, 2009

 

Homework:

 

Text Books Covered (9-4)
Rules and Regulations Signed and Returned (9-2)
Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Text Book Scavenger Hunt (9-2)
Read Section 1.1 and 1.4 (9-2)

 
Classwork:
 
Period 7:
 
no class
 
Period 8:
 
no class
 

 

September 2, 2009

 

Homework:

 

Text Books Covered (9-4)
Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Read Section 1.1,1.3, and 1.4 (9-4)
Lab Safety Skits (9-10)
Lab Equipment Sketches (9-9)
Safety Contract signed and returned (9-4)

 
Classwork:
 
Period 7:
 
no class
 
Period 8:
 
Introduction to unit analysis
 

Units of Measurement

 

-         All measurements must include both a unit and a number.

o       Without the unit, the number has no meaning.

-         English vs. Metric System:

o       English system – feet, inches, etc are not used in science.

o       Metric system- the international system of measurement is used

§         Common language for all scientists

§         Easy conversions

 

SI Base Unit

 

 

 

 

 

Physical Quantity

 

Unit Name and Symbol

mass

 

kilogram, kg

length

 

meter, m

time

 

second, s

count, quantity

 

mole, mol

temperature

 

kelvin, K

electric current

 

ampere, A

luminous intensity

 

candela, cd

 

 

 

Derived Units Commonly Used in Chemistry

 

 

 

Physical Quantity

 

Unit Name and Symbol

area

 

square meter

volume

 

cubic meter

force

 

newton, N

pressure

 

pascal, Pa

energy

 

joule, J

power

 

watt, W

voltage

 

volt, V

frequency

 

hertz, Hz

electric charge

 

coulomb, C

 

The International System of Units (SI)

-         Seven base units (shown above)

 

Definitions:

o       Length: distance that light travels in a vacuum during a time interval 1/299,792,458 of a second

o       Mass and weight:

§         Mass: amount of material- about 2.2 lbs at sea level

§         Weight: influence of the force of gravity on mass

o       Area and Volume (derived units – combinations of base units)

§         Area = Length x Width

5.0 m x 3.0 m = 15 m2

·        Both units and numbers are multiplied in the answer

§         Volume: amount of space that an object occupies

 

Non- SI Units Used Frequently in Chemistry

-         Volume: liter, L (there are exactly 1000 L in one cubic meter)

-         Pressure: atmosphere, atm; millimeters of mercury, mm Hg

-         Temperature: Celcius degree

-         Energy: calorie, cal

 

Metric Prefixes

-         Prefixes added to the base unit that make the units larger or smaller

 

Prefixes that make the Unit Larger

o       kilo (1 km = 1000 m)

o       mega (1Mm = 1000000 m)

 

Prefixes that make the Unit Smaller

o       deci (1 dm = .1 m   or   10 dm = 1m)

o       centi (1cm = .01m)

o       milli (1mm = .001 m)

o       micro (1mm = .000001 m)

o       nano (1 nm = .000000001 m)

o       pico (1pm .000000000001 m)

Four Step Problem Solving Strategy:

  1. Analyze – read problem, identify the unknown quantities.  Organize information into a table or list.  Sketch picture or diagram to help.
  2. Plan – is the problem similar to previous problems?  Write down any equations that link the unknown and given information.  Estimate and ask yourself, does the answer seem reasonable.
  3. Solve – perform calculations.  Make sure to check units and significant digits.
  4. Evaluate – does the answer make sense.  Compare the answer to the estimate.

Unit Equations and Unit Factors

 

Based on equivalent relationships

-         statement of a relationship between two quantities that are equal

-         will be used during unit conversions

 

Example: 1 dime = 10 pennies

 

Unit Equations:

            Is a series of two equivalent quantities

           

            Ex:       1 dime = 10 pennies

                        10 pennies = 1 dime

 

Unit Factor:

            Ratio of two equivalent quantities

 

            Ex: 1dime/ 10 pennies or 10 pennies/ 1 dime

           

            Both the quantity and the reciprocal are true.

 

Exactly Equivalent Equations:

These equations are equivalent by definition, such as 1 foot is equal to exactly 12 inches.

 

As a result, rules for significant figures do not apply to these quantities are not considered when rounding for significant figures when doing the calculation.

 

A three lined equal sign is used to express these quantities.

 

            Unit Analysis:

                        Also known as dimensional analysis or the factor label method.

 

                        A simple three step process:

 

                        Step 1:

Read the problem, determine the units needed in the answer

Step 2:

Read the problem, determine which measurements given relate to the answer.

                        Step 3:

Use Unit Factors and exact equivalents to convert units through the equation to reach the desired answer units.

 

 

 

 

September 3, 2009

 

Homework:

 

Text Books Covered (9-4)
Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Read Section 1.1,1.3, and 1.4 (9-4)
Lab Safety Skits (9-10)
Lab Equipment Sketches (9-9)
Safety Contract signed and returned (9-4)

Unit Analysis Wkst 1 C/D (9-4)

 
Classwork:
 
Period 7:
 
class time to go over Unit Analysis Wkst 1-b
 
Period 8:
 
no class

 

 

 

September 4, 2009

 

Homework:

 

Ion Quiz 1-18 (9-17)
Element Icosohedron (10-13)
Lab Safety Skits (9-10)
Lab Equipment Sketches (9-9)

Unit Analysis Wkst 1 C/D (9-4)

Sig Fig Worksheet (9-8)

 
Classwork:
 
Period 7:
 

Uncertainty in Measurement

 

*** When making a measurement, you must give all the certain (or exact) digits that the instrument can give + one additional “uncertain” digit that you estimate***

 

-         Measuring instruments always have some built in flaws

-         Measurement always involves some estimation

 

On an electronic balance:

-         The measurement is done for you.  The last number on the screen is the uncertain digit

o       Be sure to include the unit as well as the measurement

 

On a scale:

-         Imagine a graduated cylinder- measures volume

o       Liquids curve in the cylinder (known as the meniscus)

o       Measurements are taken from the bottom of the bend

-         The certain digits are those given on the graduated cylinder.

o       The uncertain digit is found by reading between the lines of the instrument

 

The Uncertainty of a Measurment

-         Generally, the uncertainty of a measurement reflects the value of the uncertain digit:

Suppose the measurement was: 32.7 mL

§         The seven in this measurement is uncertain.

§         Since the seven is uncertain, it could possibly as high as an 8 or as low as a 6.

§         Therefore the uncertainty is +/- .1

 

Reliability in Measurement

 

-         Precision- several measurements that are close in value

-         Accuracy- how close a measurement is to the accepted value (a standard)

 

Reliable measurements have both high precision and high accuracy.

Can you have one without the other???

 

1-6 Significant Digits

 

-         When combining numbers in calculations, the uncertainty of the measurements must be considered in the final answer- this is done by keeping tract of significant figures

 

-         Significant digits: The certain digits and the uncertain digit make up the significant digits

 

Non- Significant Zeros:

-         As a place keeper- not significant:

o       If the zero is not a known digit, or an estimated digit, the number is not significant

-         Zeros to the Right of a number without a decimal point:

1040 – 3 significant figures

1040. – 4 significant figures

104 – 3 significant figures

1000 – 1 significant figure

1000. – 4 significant figures

1000 – 2 significant figures (the line tells that that zero is the uncertain digit.

-         The Atlantic Pacific rule???

 

More Information on Zeros:

 

Zeros to the right of the decimal place before a whole number are not significant.  .001 has only one significant figure. .0000001 also only has one significant figure.

 

Zeros between two whole numbers are significant.  1.01, now has 3 significant figures.  .0101 also has 3 significant figures.

 

Numbers following a whole number:

If a decimal place is not present, the zeros to the right of the number are not significant unless marked with a bar.  So, 1000 has only one significant figure.

 

If a decimal place is present, the zeros to the right of the number are significant.  So 1000. has 4 significant figures.

 

Zeros following a whole number after a decimal are significant. So, in the number 14.000 the three zeros are significant so there are 5 significant figures.  .0002012300 has 7 significant figures.  Remember, those first three zeros are not significant, but the ones following the three are significant.

 

Significant Digits in Calculations:

 

            Rule for exact numbers

           

When an exact number appears in a calculation, it does not effect the significant digits of the calculations

           

                        **All Defined Value Unit Factors are Exact Numbers**

 

            Rule for addition and subtraction of measurements:

 

Find the measurement with the most uncertainty (fewest number of decimal places) and round the answer to that uncertainty.

 

Ex.  4.5 g + 3.221 g + 4.3232 g = ?

 

            4.5 has an uncertainty of .1

            3.221 has an uncertainty of .001

            4.3232 has an uncertainty of .0001

 

So, the number with the most uncertainty is 4.5 with an uncertainty of .1, therefore, the answer must be rounded off to that uncertainty (in this case, one decimal place)

 

The Math: 

12.0442 is the answer so far, but remember to correct for uncertainty the answer may only have one decimal place.  In this case, 0 should be the last significant figure.  Look to the right of zero, notice that it is a four.  Since it is a four, we need to round that four down.  The zero does not change, so the answer to the question would become 12.0 +/- .1 g.

 

            Rule for multiplication or division of measurements:

                       

Find the measurement with the fewest number of significant figures and round the answer to that number of significant figures.

                        Ex. 5.32 g x .01 g

                                   

5.32 has 3 significant figures and .01 has 1 significant figure, so the answer to the problem must have only one significant figure.

 

The answer is .0532.  Remember, now you need to correct for significant figures.  Since the answer can only have one significant figure, anything after the 5 must be rounded off.  Since 3 is less than five, it is rounded down, and the five does not change.  The answer to this problem then is .05 (one significant figure).

 

Scientific notation:

 

Scientific measurements usually appear in the form of scientific notation, written in the general form as:

 

t.tt x 10n  where t is any integer and n is the some whole number of times that 10 has been multiplied to reach a given answer.

 

Rule # 1

Find the first non-zero significant figure in a number and place the decimal place immediately to the right of that number.

                        Rule # 2

IF the decimal was moved to the left, then the power of 10 is a positive number

 

IF the decimal was moved to the right, then the power of 10 is a negative number

 

Remove all non-significant numbers (place holding zeros)

 

Example:

 

Write .00923 in scientific notation:

 

Ok, since the 2 zeros are place holders, they will not appear in the final answer.

 

The fist non-zero sig fig is the 9, so place the decimal after the 9

            9.23

Now, since the decimal was moved to the right 3 places, the power of ten is a – number

 

                                    9.23 x 10-3

            Write 5600 in scientific notation:

 

Ok, the first sig fig is the 5, so place the decimal immediately to the right of the 5

                                                            5.600

           

Since the two zeros are not significant, they should not appear in the final answer:

 

            5.6

 

Since the decimal was moved to the left three place, the power of 10 is a positive number:

 

5.6 x 103 (to check to see if you have done this correctly simply revert to the ordinary number)

 

Since 103 is 10 x 10 x 10, 5.6 is being multiplied by 1000.  when 5.6 is multiplied by 1000, the answer becomes 5600

 

 

Period 8:
 
class time to work on sig figs worksheet; safety skit;